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Title: Temperature dependence of the rate constants of the reactions of oxygen atoms with trans-2-butene, cis-2-butene, 2-methylpropene, 2-methyl-2-butene, and 2,3-dimethyl-2-butene
Journal: Int. J. Chem. Kinet.
Volume: 27
Page(s): 277 - 285
Year: 1995
Reference type: Journal article
Squib: 1995BIE/BIT277-285
Reaction:
(CH3)2C=CHCH3 + O· → Products
Reaction order:
2
Temperature:
201 - 369
K
Pressure: 7.40E-3 - 8.00E-3 bar
Rate expression:
2.34x10-11 [±1.64x10-12 cm3/molecule s] e2079 [±125 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Chemiluminescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 201 | 8.12E-11 |
| 225 | 7.11E-11 |
| 250 | 6.36E-11 |
| 275 | 5.81E-11 |
| 300 | 5.39E-11 |
| 325 | 5.05E-11 |
| 350 | 4.78E-11 |
| 369 | 4.61E-11 |