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Accessibility information
Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Products and Mechanism of the Reaction of Cl with Butanone in N2/O2 Diluent at 297-526 K
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   2424 - 2437
Year:   2009
Reference type:   Journal article
Squib:   2009KAI/WAL2424-2437

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → Products  297 - 475   4.00E-11           4.00E-11  2
  2009KAI/WAL2424-2437   ·CH2C(O)C2H5 + Cl2 → CH2ClC(O)C2H5 + ·Cl  297   0.03              2
  Reference reaction:  ·CH2C(O)C2H5 + O2 → Products 2
  2009KAI/WAL2424-2437   Cl2 + CH3C(O)CH(·)CH3 → 2-Butanone, 3-chloro- + ·Cl  297   0.01              2
  Reference reaction:  O2 + CH3C(O)CH(·)CH3 → Products 2
  2009KAI/WAL2424-2437   Cl2 + ·CH2CH2C(O)CH3 → CH3C(O)CH2CH2Cl + ·Cl  297   1.52              2
  Reference reaction:  O2 + ·CH2CH2C(O)CH3 → Products 2
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → HCl + CH3C(O)CH(·)CH3  297   2.90E-11              2
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → HCl + ·CH2CH2C(O)CH3  297   8.60E-12              2
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → ·CH2C(O)C2H5 + HCl  297   1.20E-12              2
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → HCl + ·CH2CH2C(O)CH3  297   1.90E-11       1966      2
  2009KAI/WAL2424-2437   C2H5COCH3 + ·Cl → ·CH2C(O)C2H5 + HCl  297   2.30E-11       7531      2
  2009KAI/WAL2424-2437   (CH3)CH(OO·)COCH3 → O2 + CH3C(O)CH(·)CH3  297   5.63E16       1.03E05      1
  2009KAI/WAL2424-2437   (CH3)CH(OO·)COCH3 + (CH3)CH(OO·)COCH3 → (CH3CO)2 + CH3CH(OH)C(O)CH3 + O2  297   1.08E-13       7740      2
  2009KAI/WAL2424-2437   CH3C(O)CH2CH2OO· + (CH3)CH(OO·)COCH3 → Other Products + (CH3CO)2 + O2  297   1.96E-13       7740      2
Search returned 12 records.