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Author(s):   Arutyunov, V.S.; Gorshenev, S.I.; Chaikin, A.M.
Title:   Rate constants for the interaction of trifluoromethyl radicals with oxygen and fluorine
Journal:   React. Kinet. Catal. Lett.
Volume:   6
Page(s):   161 - 167
Year:   1977
Reference type:   Journal article
Squib:   1977ARU/GOR161-167

Reaction:   ·CF3 + O2CF3O2
Reaction order:   2
Reference reaction:   ·CF3 + Cl2CF3Cl + ·Cl
Reference reaction order:   2
Temperature:   296 - 356 K
Pressure:  1.07E-2 - 0.13 bar
Rate expression:   3.6±6.8 e6693 [±8314472 J/mole]/RT
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
296 5.46E1
300 5.27E1
325 4.29E1
350 3.59E1
356 3.45E1