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 Author(s):   Skorobogatov, G.A.; Dymov, B.P.; Tedeev, R.S.
Title:   Measurement of rate constants and equilibrium constants of RI = R + I and I + RI = I2 + R for R = C3F7, iso-C3F7, C6F13, CF3OCF2CF2 or C3F7OCF2CF2
Journal:   J. Gen. Chem. USSR
Volume:   61
Page(s):   158 - 165
Original page:   178
Year:   1991
Reference type:   Journal article
Squib:   1991SKO/DYM158-165

Reaction:   CF3CF2CF2I → CF3CF2CF2· + I
Reaction order:   1
Temperature:   560 - 700 K
Rate expression:   1.26x1015 [s-1] e-211188 [±2112 J/mole]/RT
Uncertainty:   1.58000004
Bath gas:   CF3CF2CF2I
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
560 2.52E-5
575 8.24E-5
600 5.19E-4
625 2.82E-3
650 1.35E-2
675 5.73E-2
700 2.20E-1