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Author(s):   Cadman, P.; Owen, H.L.
Title:   Abstraction of chlorine and bromine atoms from alkyl halides by the trifluorosiyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   77
Page(s):  
Year:   1981
Reference type:   Journal article
Squib:   1981CAD/OWE1913

Reaction:   tert-C4H9Cl + SiF3tert-C4H9 + SiClF3
Reaction order:   2
Reference reaction:   C2H5Cl + SiF3·C2H5 + SiClF3
Reference reaction order:   2
Temperature:   468 - 538 K
Pressure:  1.01 bar
Rate expression:   1.27±3.6x10-1 e15881 [±1272 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
468 7.52E1
475 7.08E1
500 5.79E1
525 4.83E1
538 4.42E1