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Author(s):   Lefort, B.; Tsang, W.
Title:   High temperature stability of larger aromatic compounds
Journal:   Combust. Flame
Volume:   158
Page(s):   657 - 665
Year:   2011
Reference type:   Journal article
Squib:   2011LEF/TSA657-665

Reaction:   ·CH3 + PhenylToluene
Reaction order:   2
Reference reaction:   ·CH3 + Phenyl → Products
Reference reaction order:   2
Temperature:   1000 - 2000 K
Pressure:  0.10 - 100 bar
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   A kinetic model using an RRKM / master equation analysis has been developed based on the analysis of the earlier literature sources and analogies with similar reactions. Pressure dependence of the branching ratio was calculated for different temperatures between the pressures of 0.1 and 100 bar; it is presented in a tabular format.

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