Author(s):   Husain, D.; Marshall, P.
Title:   Determination of absolute rate data for the reactions of atomic sodium, Na(3²S₁_/₂), with CH₃F, CH₃Cl, CH₃Br, HCl, and HBr as a function of temperature by time-resolved atomic resonance spectroscopy
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):
Year:   1986
Reference type:   Journal article
Squib:   1986HUS/MAR83

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1986HUS/MAR83	CH₃Br + Na → ·CH₃ + NaBr	683 - 889	4.00E-10	1.80E04	2
1986HUS/MAR83	CH₃Cl + Na → ·CH₃ + NaCl	770 - 892	8.00E-10	4.40E04	2
1986HUS/MAR83	CH₃F + Na → ·CH₃ + NaF	804 - 923	7.01E-10	8.20E04	2
1986HUS/MAR83	Na + HCl → NaCl + H·	719 - 966	4.00E-10	3.40E04	2
1986HUS/MAR83	Na + HBr → NaBr + H·	537 - 885	1.48E-11		2

Search returned 5 records.