Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Cohen, N.; Westberg, K.R.
Title:   Chemical kinetic data sheets for high-temperature reactions. Part II
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   1211 - 1311
Year:   1991
Reference type:   Journal article
Squib:   1991COH/WES1211-1311

Reaction:   iso-C4H10 + tert-C4H9 + ·OH
Reaction order:   2
Reference reaction:   iso-C4H10 + ·OH + iso-C4H9
Reference reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   6.55x10-2(T/298 K)0.10 e19290 [J/mole]/RT
Uncertainty:   3.16000009
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 1.58E2
300 1.50E2
400 2.23E1
500 7.14E0
600 3.36E0
700 1.96E0
800 1.31E0
900 9.63E-1
1000 7.52E-1
1100 6.15E-1
1200 5.20E-1
1300 4.52E-1
1400 4.01E-1
1500 3.62E-1
1600 3.30E-1
1700 3.05E-1
1800 2.85E-1
1900 2.67E-1
2000 2.53E-1