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Title: Kinetics and Mechanisms of the Tropospheric Reactions of Menthol, Borneol, Fenchol, Camphor, and Fenchone with Hydroxyl Radicals (OH) and Chlorine Atoms (Cl)
Journal: J. Phys. Chem. A
Volume: 116
Page(s): 4097 - 4107
Year: 2012
Reference type: Journal article
Squib: 2012CEA/BAL4097-4107
Reaction:
Cyclohexanol + ·Cl → Products
Reaction order:
2
Temperature:
298
K
Pressure: 0.96 bar
Rate expression:
3.21x10-10 [±2.6x10-11 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Time resolution:
By end product analysis
Analytical technique:
Fourier transform (FTIR)
Comments:
The reported error is twice the standard deviation. 1-butene and propene were used as reference compounds.
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