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Author(s):   Kelly, T.; Bossoutrot, V.; Magneron, I.; Wirtz, K.; Treacy, J.; Mellouki, A.; Sidebottom, H.; Le Bras, G.
Title:   A kinetic and mechanistic study of the reactions of OH radicals and Cl atoms with 3,3,3-trifluoropropanol under atmospheric conditions
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   347 - 355
Year:   2005
Reference type:   Journal article
Squib:   2005KEL/BOS347-355

Reaction:   CF3CH2C(O)H + ·Cl → Products
Reaction order:   2
Reference reaction:   HC(O)OC2H5 + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.92±3.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Cl generated by the 254-nm photolysis of Cl2.
FTIR also employed for analysis.

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