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Author(s):   Gierczak, T.; Talukdar, R.K.; Herndon, S.C.; Vaghjiani, G.L.; Ravishankara, A.R.
Title:   Rate coefficients for the reactions of hydroxyl radicals with methane and deuterated methanes
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   3125 - 3134
Year:   1997
Reference type:   Journal article
Squib:   1997GIE/TAL3125-3134

Reaction:   CH2D2 + ·OH → Products
Reaction order:   2
Temperature:   270 - 354 K
Pressure:  0.13 bar
Rate expression:   2.18x10-12 [cm3/molecule s] e-16047 [±2079 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
270 1.71E-15
275 1.95E-15
300 3.50E-15
325 5.73E-15
350 8.76E-15
354 9.33E-15