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Author(s):   Dusoleil, S.; Goldfinger, P.; Mahieu-Van Der Auwera, A.M.; Martens, G.; Van Der Auwera, D.
Title:   Elementary rate constants in atomic chlorination reactions. Part 1.-Experiments in intermittent light
Journal:   Trans. Faraday Soc.
Volume:   57
Page(s):   2197 - 2209
Year:   1961
Reference type:   Journal article
Squib:   1961DUS/GOL2197-2209

Reaction:   C2Cl5 + Cl2CCl3CCl3 + ·Cl
Reaction order:   2
Temperature:   360 - 520 K
Pressure:  4.00E-2 - 0.24 bar
Rate expression:   3.39x10-13 [cm3/molecule s] e-9894 [J/mole]/RT
Bath gas:   Cl2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
360 1.24E-14
375 1.42E-14
400 1.73E-14
425 2.06E-14
450 2.41E-14
475 2.77E-14
500 3.14E-14
520 3.44E-14