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Author(s):   Tschuikow-Roux, E.; Niedzielski, J.
Title:   Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group
Journal:   J. Photochem.
Volume:   27
Page(s):   141 - 150
Year:   1984
Reference type:   Journal article
Squib:   1984TSC/NIE141-150

Reaction:   ·Cl + CH2DCH2Cl → CH2DCHCl(.) + HCl
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   282 - 368 K
Pressure:  2.67E-2 bar
Rate expression:   1.31±2.6x10-2 e9312 [±33.26 J/mole]/RT
Bath gas:   CH2DCH2Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
282 6.95E1
300 5.48E1
325 4.11E1
350 3.21E1
368 2.75E1