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Accessibility information
Author(s):   Cillien, C.; Goldfinger, P.; Huybrechts, G.; Martens, G.
Title:   Hydrogen abstraction from chlorinated ethanes by chlorine atoms
Journal:   Trans. Faraday Soc.
Volume:   63
Page(s):   1631 - 1635
Year:   1967
Reference type:   Journal article
Squib:   1967CIL/GOL1631-1635

Reaction:   CH3CCl3 + ·ClHCl + CCl3CH2
Reaction order:   2
Reference reaction:   CH3Cl + ·Cl·CH2Cl + HCl
Reference reaction order:   2
Temperature:   323 - 423 K
Pressure:  0.20 - 2.72 bar
Rate expression:   7.0x10-2 e-1247 [±1039 J/mole]/RT
Uncertainty:   1.40999997
Bath gas:   H2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
323 4.40E-2
325 4.41E-2
350 4.56E-2
375 4.69E-2
400 4.81E-2
423 4.91E-2