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Accessibility information
Author(s):   Wine, P.H.; Semmes, D.H.; Ravishankara, A.R.
Title:   Upper limit for the rate of reaction of Cl(2Pj) with methyl chloroform
Journal:   Chem. Phys. Lett.
Volume:   90
Page(s):   128 - 132
Year:   1982
Reference type:   Journal article
Squib:   1982WIN/SEM128-132

Reaction:   CH3CCl3 + ·ClHCl + CCl3CH2
Reaction order:   2
Temperature:   259 - 356 K
Pressure:  0.13 bar
Rate expression:   1.71x10-12 [cm3/molecule s] e-9312 [J/mole]/RT
Rate constant is an upper limit.
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
259 2.26E-14
275 2.91E-14
300 4.09E-14
325 5.45E-14
350 6.97E-14
356 7.36E-14