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Author(s):   Talhaoui, A.; Louis, F.; Devolder, P.; Meriaux, B.; Sawerysyn, J.P.
Title:   Rate coefficients of the reactions of chlorine atoms with haloethanes of type CH3CCl3-xFx (x=0, 1, and 2): experimental and ab initio theorical studies
Journal:   J. Phys. Chem.
Volume:   100
Page(s):   13531 - 13538
Year:   1996
Reference type:   Journal article
Squib:   1996TAL/LOU13531-13538

Reaction:   CH3CCl3 + ·ClHCl + CCl3CH2
Reaction order:   2
Temperature:   298 - 416 K
Pressure:  2.67E-3 - 6.67E-3 bar
Rate expression:   2.81x10-12 [±1.66x10-12 cm3/molecule s] e-14883 [±2677 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 6.91E-15
300 7.19E-15
325 1.14E-14
350 1.69E-14
375 2.37E-14
400 3.20E-14
416 3.80E-14