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 Author(s):   Atkinson, R.; Baulch, D.L.; Cox, R.A.; Hampson, R.F., Jr.; Kerr, J.A.; Rossi, M.J.; Troe, J.
Title:   Evaluated kinetic and photochemical data for atmospheric chemistry: supplement VI. IUPAC subcommittee on gas kinetic data evaluation for atmospheric chemistry
Journal:   J. Phys. Chem. Ref. Data
Volume:   26
Page(s):   1329 - 1499
Year:   1997
Reference type:   Journal article
Squib:   1997ATK/BAU1329-1499

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997ATK/BAU1329-1499   O(1D) + H2 → ·OH + H·  200 - 350   1.10E-10           1.10E-10  2
  1997ATK/BAU1329-1499   O(1D) + N2 → N2 + O·  100 - 350   1.79E-11       -890   2.57E-11  2
  1997ATK/BAU1329-1499   O(1D) + N2 → N2O  298   9.02E-37           9.02E-37  3
  1997ATK/BAU1329-1499   O(1D) + H2O → ·OH + ·OH  200 - 350   2.19E-10           2.19E-10  2
  1997ATK/BAU1329-1499   O(1D) + O2 → O2 + O·  200 - 350   3.20E-11       -557   4.01E-11  2
  1997ATK/BAU1329-1499   O(1D) + N2O → N2 + O2  200 - 350   4.40E-11           4.40E-11  2
  1997ATK/BAU1329-1499   O(1D) + N2O → NO + NO  200 - 350   7.21E-11           7.21E-11  2
  1997ATK/BAU1329-1499   O(1D) + O3 → Products  100 - 400   2.41E-10           2.41E-10  2
  1997ATK/BAU1329-1499   O2(1DELTA) → O2  100 - 450   3.01E-18       1663   1.54E-18  2
  1997ATK/BAU1329-1499   O2(1DELTA) → O2  298   <2.01E-20           2.01E-20  2
  1997ATK/BAU1329-1499   O2(1DELTA) → O2  298   5.00E-18           5.00E-18  2
  1997ATK/BAU1329-1499   O2(1DELTA) → O2  298   <1.40E-19           1.40E-19  2
  1997ATK/BAU1329-1499   O2(1DELTA) + O3 → O2 + O2 + O·  280 - 360   5.20E-11       2.36E04   3.77E-15  2
  1997ATK/BAU1329-1499   CH3SCH2OO· + CH3SCH2OO· → Products  298   <8.00E-12           8.00E-12  2
  1997ATK/BAU1329-1499   CH3SCH2OO· + NO → CH3SCH2O· + NO2  298   1.91E-11           1.91E-11  2
  1997ATK/BAU1329-1499   CH3SCH2OO· + NO2 → CH3SCH2OONO2  298   9.00E-12           9.00E-12  2
  1997ATK/BAU1329-1499   cis-HONO + ·OH → H2O + NO2  290 - 380   2.71E-12       -2162   6.48E-12  2
  1997ATK/BAU1329-1499   CH3SH + HO2 → Products  298   <4.00E-15           4.00E-15  2
  1997ATK/BAU1329-1499   CH3SH + ·OH → Products  240 - 430   9.90E-12       -2960   3.27E-11  2
  1997ATK/BAU1329-1499   CH3SH + NO3 → Products  250 - 370   9.22E-13           9.22E-13  2
  1997ATK/BAU1329-1499   CH3SH + ·Cl → Products  190 - 430   1.20E-10       -1247   1.99E-10  2
  1997ATK/BAU1329-1499   CS2 + ·OH → COS + SH  298   <2.01E-15           2.01E-15  2
  1997ATK/BAU1329-1499   CS2 + ·OH → CS2OH  250 - 300   8.00E-12           8.00E-12  2
  1997ATK/BAU1329-1499   CS2 + ·OH → CS2OH  250 - 320   8.00E-31           8.00E-31  3
  1997ATK/BAU1329-1499   CS2 + NO3 → Products  298   <1.00E-15           1.00E-15  2
  1997ATK/BAU1329-1499   CS2 + O· → Products  210 - 500   3.20E-11       5404   3.62E-12  2
  1997ATK/BAU1329-1499   CS2 + ·Cl → Products  298   <4.00E-15           4.00E-15  2
  1997ATK/BAU1329-1499   (CH3)2S + HO2 → Products  298   <5.00E-15           5.00E-15  2
  1997ATK/BAU1329-1499   (CH3)2S + ·OH → H2O + CH3SCH2  240 - 400   1.13E-11       2104   4.84E-12  2
  1997ATK/BAU1329-1499   (CH3)2S + ·OH → (CH3)2S.OH  298   1.69E-12           1.69E-12  2
  1997ATK/BAU1329-1499   (CH3)2S + O3 → Products  298   <1.00E-18           1.00E-18  2
  1997ATK/BAU1329-1499   (CH3)2S + IO → Products  298   1.20E-14           1.20E-14  2
  1997ATK/BAU1329-1499   (CH3)2S + NO3 → HNO3 + CH3SCH2  250 - 380   1.91E-13       -4324   1.09E-12  2
  1997ATK/BAU1329-1499   (CH3)2S + ClO → Products  298   9.00E-15           9.00E-15  2
  1997ATK/BAU1329-1499   (CH3)2S + BrO → Products  240 - 320   1.50E-14       -7026   2.56E-13  2
  1997ATK/BAU1329-1499   (CH3)2S + O· → ·CH3 + CH3SO  270 - 560   1.30E-11       -3401   5.13E-11  2
  1997ATK/BAU1329-1499   (CH3)2S + ·Cl → Products  298   3.30E-10           3.30E-10  2
  1997ATK/BAU1329-1499   COS + ·OH → Products  250 - 490   1.10E-13       9977   1.96E-15  2
  1997ATK/BAU1329-1499   COS + NO3 → Products  298   <1.00E-16           1.00E-16  2
  1997ATK/BAU1329-1499   COS + O· → CO + SO  230 - 500   1.60E-11       1.79E04   1.18E-14  2
  1997ATK/BAU1329-1499   COS + ·Cl → CO + SCl  298   <1.00E-16           1.00E-16  2
  1997ATK/BAU1329-1499   (CH3S)2 + ·OH → Products  250 - 370   7.01E-11       -2910   2.27E-10  2
  1997ATK/BAU1329-1499   (CH3S)2 + NO3 → Products  300 - 380   7.01E-13              2
  1997ATK/BAU1329-1499   (CH3S)2 + O· → CH3S· + CH3SO  290 - 570   6.51E-11       -2079   1.51E-10  2
  1997ATK/BAU1329-1499   H2 + ·OH → H2O + H·  200 - 450   7.69E-12       1.75E04   6.69E-15  2
  1997ATK/BAU1329-1499   CS + O2 → Products  298   2.91E-19           2.91E-19  2
  1997ATK/BAU1329-1499   CS + O3 → COS + O2  298   3.01E-16           3.01E-16  2
  1997ATK/BAU1329-1499   CS + NO2 → COS + NO  298   7.61E-17           7.61E-17  2
  1997ATK/BAU1329-1499   CS + O· → CO + S  150 - 300   2.71E-10       6319   2.11E-11  2
  1997ATK/BAU1329-1499   HO2 + HO2 → H2O2 + O2  230 - 420   2.19E-13       -4989   1.64E-12  2
  1997ATK/BAU1329-1499   HO2 + HO2 → H2O2 + O2  230 - 420   1.90E-33       -8148   5.09E-32  3
  1997ATK/BAU1329-1499   HO2 + HO2 → H2O2 + O2  298   4.49E-32           4.49E-32  3
  1997ATK/BAU1329-1499   HO2 + ·OH → H2O + O2  250 - 400   4.80E-11       -2079   1.11E-10  2
  1997ATK/BAU1329-1499   HO2 + SO2 → Products  298   <1.00E-18           1.00E-18  2
  1997ATK/BAU1329-1499   HO2 + H2S → Products  298   <3.01E-15           3.01E-15  2
  1997ATK/BAU1329-1499   HO2 + O3 → ·OH + O2 + O2  250 - 350   1.40E-14       4989   1.87E-15  2
  1997ATK/BAU1329-1499   HO2 + NO → ·OH + NO2  200 - 400   3.40E-12       -2245   8.42E-12  2
  1997ATK/BAU1329-1499   HO2 + NO2 → HO2NO2  220 - 360   4.70E-12           4.70E-12  2
  1997ATK/BAU1329-1499   HO2 + NO2 → HO2NO2  220 - 360   1.80E-31   -3.20       1.80E-31  3
  1997ATK/BAU1329-1499   HO2 + H· → H2 + O2  245 - 300   5.60E-12           5.60E-12  2
  1997ATK/BAU1329-1499   HO2 + H· → ·OH + ·OH  245 - 300   7.21E-11           7.21E-11  2
  1997ATK/BAU1329-1499   HO2 + H· → H2O + O·  245 - 300   2.41E-12           2.41E-12  2
  1997ATK/BAU1329-1499   HO2 + NO3 → Products  298   4.00E-12           4.00E-12  2
  1997ATK/BAU1329-1499   HO2 + O· → ·OH + O2  220 - 400   2.71E-11       -1862   5.74E-11  2
  1997ATK/BAU1329-1499   ·OH + ·OH → H2O2  200 - 400   2.61E-11           2.61E-11  2
  1997ATK/BAU1329-1499   ·OH + ·OH → H2O2  200 - 400   6.89E-31   -0.80       6.89E-31  3
  1997ATK/BAU1329-1499   ·OH + ·OH → H2O + O·  200 - 500   7.89E-14   2.60   -7857   1.88E-12  2
  1997ATK/BAU1329-1499   ·OH + SO2 → HOSO2  200 - 300   2.01E-12           2.01E-12  2
  1997ATK/BAU1329-1499   ·OH + SO2 → HOSO2  300 - 400   4.00E-31   -3.30          3
  1997ATK/BAU1329-1499   ·OH + NH3 → H2O + ·NH2  230 - 450   3.50E-12       7691   1.57E-13  2
  1997ATK/BAU1329-1499   ·OH + HNO3 → H2O + NO3  298   1.50E-13           1.50E-13  2
  1997ATK/BAU1329-1499   ·OH + H2O2 → HO2 + H2O  240 - 460   2.91E-12       1330   1.70E-12  2
  1997ATK/BAU1329-1499   ·OH + H2S → H2O + SH  220 - 520   6.09E-12       665   4.66E-12  2
  1997ATK/BAU1329-1499   ·OH + O3 → HO2 + O2  220 - 450   1.91E-12       8314   6.66E-14  2
  1997ATK/BAU1329-1499   ·OH + NO → cis-HONO  200 - 400   3.30E-11           3.30E-11  2
  1997ATK/BAU1329-1499   ·OH + NO → cis-HONO  200 - 400   7.42E-31   -2.40       7.42E-31  3
  1997ATK/BAU1329-1499   ·OH + NO2 → HNO3  200 - 400   7.51E-11   -0.60       7.51E-11  2
  1997ATK/BAU1329-1499   ·OH + NO2 → HNO3  200 - 400   2.60E-30   -2.90       2.60E-30  3
  1997ATK/BAU1329-1499   ·OH + NO3 → HO2 + NO2  298   2.01E-11           2.01E-11  2
  1997ATK/BAU1329-1499   ·OH + O· → O2 + H·  220 - 500   2.31E-11       -915   3.34E-11  2
  1997ATK/BAU1329-1499   ·OH + HO2NO2 → Products  240 - 340   1.50E-12       -2993   5.02E-12  2
  1997ATK/BAU1329-1499   CH3S· + O3 → Products  290 - 360   2.01E-12       -2411   5.32E-12  2
  1997ATK/BAU1329-1499   CH3S· + NO → CH3SNO  250 - 450   4.00E-11           4.00E-11  2
  1997ATK/BAU1329-1499   CH3S· + NO → CH3SNO  250 - 450   3.20E-29   -4.00       3.20E-29  3
  1997ATK/BAU1329-1499   CH3S· + NO2 → NO + CH3SO  240 - 350   2.01E-11       -2661   5.88E-11  2
  1997ATK/BAU1329-1499   SO2 + NO3 → Products  298   <1.00E-19           1.00E-19  2
  1997ATK/BAU1329-1499   SO2 + O· → SO3  200 - 400   4.00E-32       8314   1.39E-33  3
  1997ATK/BAU1329-1499   SO3 + NH3 → Products  298   5.80E-11           5.80E-11  2
  1997ATK/BAU1329-1499   S + O2 → SO + O·  250 - 430   2.09E-12           2.09E-12  2
  1997ATK/BAU1329-1499   S + O3 → O2 + SO  298   1.20E-11           1.20E-11  2
  1997ATK/BAU1329-1499   H2O2 + O· → HO2 + ·OH  280 - 390   1.40E-12       1.66E04   1.70E-15  2
  1997ATK/BAU1329-1499   H2O + N2O5 → HNO3 + HNO3  298   <2.01E-21           2.01E-21  2
  1997ATK/BAU1329-1499   O2 + NO + NO → NO2 + NO2  270 - 600   3.31E-39       -4407   1.96E-38  3
  1997ATK/BAU1329-1499   O2 + H· → HO2  200 - 400   7.51E-11           7.51E-11  2
  1997ATK/BAU1329-1499   O2 + H· → HO2  200 - 600   5.40E-32   -1.80       5.40E-32  3
  1997ATK/BAU1329-1499   O2 + ·NH2 → Products  298   <5.99E-21           5.99E-21  2
  1997ATK/BAU1329-1499   O2 + SO → SO2 + O·  230 - 420   1.60E-13       1.90E04   7.61E-17  2
  1997ATK/BAU1329-1499   O2 + SH → Products  298   <4.00E-19           4.00E-19  2
  1997ATK/BAU1329-1499   O2 + ·CH2SH → Products  298   6.59E-12           6.59E-12  2
  1997ATK/BAU1329-1499   O2 + O· → O3  100 - 300   5.60E-34   -2.80       5.60E-34  3
  1997ATK/BAU1329-1499   O2 + O· → O3  100 - 300   6.01E-34   -2.80       6.01E-34  3
  1997ATK/BAU1329-1499   O2 + CH3SCH2 → CH3SCH2OO·  298   5.71E-12           5.71E-12  2
  1997ATK/BAU1329-1499   O2 + HOSO2 → HO2 + SO3  290 - 430   1.30E-12       2744   4.30E-13  2
  1997ATK/BAU1329-1499   O2 + HSO2 → Products  298   3.01E-13           3.01E-13  2
  1997ATK/BAU1329-1499   O2 + HSO → Products  298   <2.01E-17           2.01E-17  2
  1997ATK/BAU1329-1499   O2 + CS2OH → Products  240 - 350   2.81E-14           2.81E-14  2
  1997ATK/BAU1329-1499   H2S + NO3 → Products  298   <1.00E-15           1.00E-15  2
  1997ATK/BAU1329-1499   H2S + ·Cl → HCl + SH  200 - 430   3.70E-11       -1729   7.44E-11  2
  1997ATK/BAU1329-1499   O3 + NO → O2 + NO2  195 - 304   1.79E-12       1.14E04   1.81E-14  2
  1997ATK/BAU1329-1499   O3 + NO2 → O2 + NO3  230 - 360   1.40E-13       2.05E04   3.52E-17  2
  1997ATK/BAU1329-1499   O3 + ·NH2 → Products  250 - 380   4.90E-12       8314   1.71E-13  2
  1997ATK/BAU1329-1499   O3 + SO → SO2 + O2  230 - 420   4.50E-12       9728   8.87E-14  2
  1997ATK/BAU1329-1499   O3 + SH → O2 + HSO  290 - 440   9.51E-12       2328   3.72E-12  2
  1997ATK/BAU1329-1499   O3 + ·CH2SH → Products  298   3.50E-11           3.50E-11  2
  1997ATK/BAU1329-1499   O3 + O· → O2 + O2  200 - 400   8.00E-12       1.71E04   7.96E-15  2
  1997ATK/BAU1329-1499   O3 + CH3SO → Products  298   5.99E-13           5.99E-13  2
  1997ATK/BAU1329-1499   O3 + CH3SS → Products  298   4.60E-13           4.60E-13  2
  1997ATK/BAU1329-1499   O3 + CH3SOO → Products  227   <8.00E-13              2
  1997ATK/BAU1329-1499   O3 + HSO → Products  298   1.10E-13           1.10E-13  2
  1997ATK/BAU1329-1499   N2O5 → NO2 + NO3  200 - 300   9.71E14   0.10   9.23E04   0.06  1
  1997ATK/BAU1329-1499   N2O5 → NO2 + NO3  200 - 400   1.00E-03   -3.50   9.15E04   9.32E-20  2
  1997ATK/BAU1329-1499   NO + NO2 → N2O3  200 - 300   7.89E-12   1.40       7.89E-12  2
  1997ATK/BAU1329-1499   NO + NO2 → N2O3  200 - 300   3.09E-34   -7.70       3.09E-34  3
  1997ATK/BAU1329-1499   NO + ·NH2 → Products  210 - 500   1.60E-11   -1.50       1.60E-11  2
  1997ATK/BAU1329-1499   NO + SH → HSN=O  250 - 300   2.71E-11           2.71E-11  2
  1997ATK/BAU1329-1499   NO + SH → HSN=O  250 - 300   2.40E-31   -2.50       2.40E-31  3
  1997ATK/BAU1329-1499   NO + NO3 → NO2 + NO2  200 - 420   1.79E-11       -915   2.59E-11  2
  1997ATK/BAU1329-1499   NO + ·CH2SH → Products  298   1.50E-11           1.50E-11  2
  1997ATK/BAU1329-1499   NO + O· → NO2  200 - 1500   3.01E-11   0.30       3.01E-11  2
  1997ATK/BAU1329-1499   NO + O· → NO2  200 - 300   1.00E-31   -1.60       1.00E-31  3
  1997ATK/BAU1329-1499   NO + CH3SOO → Products  227 - 256   1.10E-11              2
  1997ATK/BAU1329-1499   NO + HSO → Products  298   <1.00E-15           1.00E-15  2
  1997ATK/BAU1329-1499   NO2 + NO2 → N2O4  250 - 300   1.00E-12           1.00E-12  2
  1997ATK/BAU1329-1499   NO2 + NO2 → N2O4  300 - 500   1.40E-33   -3.80          3
  1997ATK/BAU1329-1499   NO2 + ·NH2 → Products  250 - 500   2.01E-11   -2.00       2.01E-11  2
  1997ATK/BAU1329-1499   NO2 + SH → NO + HSO  220 - 420   2.61E-11       -1995   5.83E-11  2
  1997ATK/BAU1329-1499   NO2 + NO3 → N2O5  200 - 500   2.01E-12   0.20       2.01E-12  2
  1997ATK/BAU1329-1499   NO2 + NO3 → N2O5  200 - 400   2.81E-30   -3.50       2.81E-30  3
  1997ATK/BAU1329-1499   NO2 + ·CH2SH → Products  298   4.40E-11           4.40E-11  2
  1997ATK/BAU1329-1499   NO2 + O· → O2 + NO  220 - 360   6.51E-12       -998   9.74E-12  2
  1997ATK/BAU1329-1499   NO2 + O· → NO3  200 - 400   2.19E-11           2.19E-11  2
  1997ATK/BAU1329-1499   NO2 + O· → NO3  200 - 400   9.02E-32   -2.00       9.02E-32  3
  1997ATK/BAU1329-1499   NO2 + CH3SO → Products  298   1.20E-11           1.20E-11  2
  1997ATK/BAU1329-1499   NO2 + CH3SS → Products  298   1.79E-11           1.79E-11  2
  1997ATK/BAU1329-1499   NO2 + CH3SOO → Products  227 - 246   2.19E-11              2
  1997ATK/BAU1329-1499   NO2 + HSO → Products  298   9.60E-12           9.60E-12  2
  1997ATK/BAU1329-1499   NO2 + CH3SSO → Products  298   4.50E-12           4.50E-12  2
  1997ATK/BAU1329-1499   N2O4 → NO2 + NO2  250 - 300   1.15E16       5.37E04   4.43E06  1
  1997ATK/BAU1329-1499   N2O4 → NO2 + NO2  300 - 500   1.30E-05   -3.80   5.32E04      2
  1997ATK/BAU1329-1499   N2O3 → NO + NO2  225 - 300   4.70E15   0.40   4.06E04   3.63E08  1
  1997ATK/BAU1329-1499   N2O3 → NO + NO2  225 - 300   1.91E-07   -8.70   4.06E04   1.48E-14  2
  1997ATK/BAU1329-1499   NO3 + O· → O2 + NO2  298   1.69E-11           1.69E-11  2
  1997ATK/BAU1329-1499   HO2NO2 → HO2 + NO2  260 - 300   5.70E15       9.31E04   0.27  1
  1997ATK/BAU1329-1499   HO2NO2 → HO2 + NO2  260 - 300   4.10E-05       8.81E04   1.46E-20  2
  1997ATK/BAU1329-1499   CS2OH → CS2 + ·OH  250 - 300   1.60E13       4.29E04   4.83E05  1
  1997ATK/BAU1329-1499   CS2OH → CS2 + ·OH  250 - 300   1.60E-06       4.29E04   4.83E-14  2
Search returned 156 records.