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 Author(s):   Ruzsicska, B.P.; Jodhan, A.; Choi, H.K.J.; Strausz, O.P.
Title:   Chemistry of carbynes: reaction of CF, CCl, and CBr with alkenes
Journal:   J. Am. Chem. Soc.
Volume:   105
Page(s):   2489 - 2490
Year:   1983
Reference type:   Journal article
Squib:   1983RUZ/JOD2489-2490

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1983RUZ/JOD2489-2490   C2H4 + CF → Products  298   6.64E-14           6.64E-14  2
  1983RUZ/JOD2489-2490   C2H4 + ·CCl → Products  298   2.66E-13           2.66E-13  2
  1983RUZ/JOD2489-2490   C2H4 + CBr → Products  298   8.63E-13           8.63E-13  2
  1983RUZ/JOD2489-2490   1-C4H8 + CF → Products  298   6.64E-13           6.64E-13  2
  1983RUZ/JOD2489-2490   1-C4H8 + ·CCl → Products  298   2.82E-12           2.82E-12  2
  1983RUZ/JOD2489-2490   1-C4H8 + CBr → Products  298   5.81E-12           5.81E-12  2
  1983RUZ/JOD2489-2490   Cyclohexene + ·CCl → Products  298   5.15E-12           5.15E-12  2
  1983RUZ/JOD2489-2490   CH3CH=CH2 + CF → Products  298   4.98E-13           4.98E-13  2
  1983RUZ/JOD2489-2490   CH3CH=CH2 + ·CCl → Products  298   1.66E-12           1.66E-12  2
  1983RUZ/JOD2489-2490   CH3CH=CH2 + CBr → Products  298   5.13E-12           5.13E-12  2
  1983RUZ/JOD2489-2490   Isobutene + CF → Products  298   1.83E-12           1.83E-12  2
  1983RUZ/JOD2489-2490   Isobutene + ·CCl → Products  298   5.81E-12           5.81E-12  2
  1983RUZ/JOD2489-2490   Isobutene + CBr → Products  298   1.33E-11           1.33E-11  2
  1983RUZ/JOD2489-2490   (CH3)2C=CHCH3 + ·CCl → Products  298   1.33E-11           1.33E-11  2
  1983RUZ/JOD2489-2490   (CH3)2C=CHCH3 + CBr → Products  298   2.82E-11           2.82E-11  2
  1983RUZ/JOD2489-2490   (CH3)2C=C(CH3)2 + ·CCl → Products  298   2.32E-11           2.32E-11  2
  1983RUZ/JOD2489-2490   (CH3)2C=C(CH3)2 + CBr → Products  298   3.82E-11           3.82E-11  2
  1983RUZ/JOD2489-2490   1,3-Cyclohexadiene + ·CCl → Products  298   2.32E-12           2.32E-12  2
  1983RUZ/JOD2489-2490   (E)-2-C4H8 + CF → Products  298   1.83E-12           1.83E-12  2
  1983RUZ/JOD2489-2490   (E)-2-C4H8 + ·CCl → Products  298   4.32E-12           4.32E-12  2
  1983RUZ/JOD2489-2490   (E)-2-C4H8 + CBr → Products  298   1.23E-11           1.23E-11  2
  1983RUZ/JOD2489-2490   1,4-Cyclohexadiene + ·CCl → Products  298   6.14E-12           6.14E-12  2
Search returned 22 records.