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Accessibility information
Author(s):   LeCalve, S.; LeBras, G.; Mellouki, A.
Title:   Temperature dependence for the rate coefficients of the reactions of the OH radical with a series of formates
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   5489 - 5493
Year:   1997
Reference type:   Journal article
Squib:   1997LEC/LEB5489-5493

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997LEC/LEB5489-5493   HC(O)OCH3 + ·OH → Products  233 - 372   8.54E-13       3833   1.82E-13  2
  1997LEC/LEB5489-5493   HC(O)OC2H5 + ·OH → Products  243 - 372   5.66E-13       -1114   8.88E-13  2
  1997LEC/LEB5489-5493   HCOOCH2CH2CH3 + ·OH → Products  253 - 372   1.65E-12       -349   1.90E-12  2
  1997LEC/LEB5489-5493   HCOO(CH2)3CH3 + ·OH → Products  253 - 371   3.64E-12       -125   3.82E-12  2
  1997LEC/LEB5489-5493   HC(O)OC(CH3)3 + ·OH → Products  253 - 372   3.59E-12       3733   7.95E-13  2

Search returned 5 records.