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Author(s):   Badenes, M.P.; Croce, A.E.; Cobos, C.J.
Title:   Falloff curves for the recombination reaction Cl+FC(O)O+M -> FC(O)OCl+M
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   3186 - 3196
Year:   2006
Reference type:   Journal article
Squib:   2006BAD/CRO3186-3196

Reaction:   ·Cl + FC(O)O· → FC(O)OCl
Reaction order:   3
Temperature:   296 K
Pressure:  6.80E-3 - 5.39E-2 bar
Rate expression:   5.9x10-28 [±1.1x10-28 cm6/molecule2 s]
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Pressure given is the partial pressure of the photolytic precursor, FC(O)OO(O)CF. The total pressure is higher.

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