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Title: Rate constants for the reactions of diolefins with OH radicals in the gas phase. Estimate of the rate constants from those for monoolefins
Journal: J. Phys. Chem.
Volume: 87
Page(s):
Year: 1983
Reference type: Journal article
Squib: 1983OHT1209
Reaction:
1,2-butadiene + ·OH → Products
Reaction order:
2
Reference reaction:
1,3-Butadiene + ·OH → Products
Temperature:
297
K
Pressure: 1.01 bar
Rate expression:
2.69x10-11 [±2.16x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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