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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   sec-C4H9CH3CH=CHCH3 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   3.16x1012 [s-1] e-154649 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 3.74E-15
400 2.02E-8
500 2.21E-4
600 1.09E-1
700 9.12E0
800 2.53E2
900 3.34E3
1000 2.64E4
1100 1.43E5
1200 5.86E5
1300 1.93E6
1400 5.37E6
1500 1.30E7
1600 2.82E7
1700 5.60E7
1800 1.03E8
1900 1.77E8
2000 2.89E8
2100 4.50E8
2200 6.73E8
2300 9.72E8
2400 1.36E9
2500 1.86E9