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Title: Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal: J. Phys. Chem.
Volume: 89
Page(s): 4600 - 4608
Year: 1985
Reference type: Journal article
Squib: 1985DEA4600-4608
Reaction:
sec-C4H9 → CH3CH=CHCH3 + H·
Reaction order:
1
Temperature:
300 - 2500
K
Rate expression:
3.16x1012 [s-1] e-154649 [J/mole]/RT
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 300 | 3.74E-15 |
| 400 | 2.02E-8 |
| 500 | 2.21E-4 |
| 600 | 1.09E-1 |
| 700 | 9.12E0 |
| 800 | 2.53E2 |
| 900 | 3.34E3 |
| 1000 | 2.64E4 |
| 1100 | 1.43E5 |
| 1200 | 5.86E5 |
| 1300 | 1.93E6 |
| 1400 | 5.37E6 |
| 1500 | 1.30E7 |
| 1600 | 2.82E7 |
| 1700 | 5.60E7 |
| 1800 | 1.03E8 |
| 1900 | 1.77E8 |
| 2000 | 2.89E8 |
| 2100 | 4.50E8 |
| 2200 | 6.73E8 |
| 2300 | 9.72E8 |
| 2400 | 1.36E9 |
| 2500 | 1.86E9 |