Author(s):   Gierczak, T.; Talukdar, R.K.; Herndon, S.C.; Vaghjiani, G.L.; Ravishankara, A.R.
Title:   Rate coefficients for the reactions of hydroxyl radicals with methane and deuterated methanes
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   3125 - 3134
Year:   1997
Reference type:   Journal article
Squib:   1997GIE/TAL3125-3134

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	n	Ea [J/mole]	k(298.00 K)	Order
1997GIE/TAL3125-3134	CH₄ + ·OH → ·CH₃ + H₂O	196 - 420	1.76E-13	2.82	8206	6.41E-15	2
1997GIE/TAL3125-3134	CH₄ + OD → ·CH₃ + HDO	223 - 420	1.40E-13	2.94	7458	6.90E-15	2
1997GIE/TAL3125-3134	CD₄ + ·OH → CD₃ + HDO	244 - 413	1.58E-13	3.01	1.28E04	9.02E-16	2
1997GIE/TAL3125-3134	CH₃D + ·OH → Products	249 - 420	4.53E-13	1.87	1.11E04	5.23E-15	2
1997GIE/TAL3125-3134	CH₂D₂ + ·OH → Products	270 - 354	2.18E-12		1.60E04	3.35E-15	2
1997GIE/TAL3125-3134	CHD₃ + ·OH → Products	270 - 354	1.46E-12		1.64E04	1.96E-15	2

Search returned 6 records.