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Accessibility information
Author(s):   Williams, R.R., Jr.; Ogg, R.A., Jr.
Title:   Kinetics of the photolysis of methyl iodide and the hydrogen halides. II. Photolysis of methyl iodide in the presence of iodine and the hydrogen halides
Journal:   J. Chem. Phys.
Volume:   15
Page(s):   696 - 702
Year:   1947
Reference type:   Journal article
Squib:   1947WIL/OGG696-702

Reaction:   ·CH3 + I2CH3I + I
Reaction order:   2
Reference reaction:   ·CH3 + HClCH4 + ·Cl
Reference reaction order:   2
Temperature:   371 - 433 K
Rate expression:   2.87x101 e10061 [J/mole]/RT
Bath gas:   HCl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
371 7.49E2
375 7.23E2
400 5.91E2
425 4.95E2
433 4.69E2