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Author(s):   Williams, R.R., Jr.; Ogg, R.A., Jr.
Title:   Kinetics of the photolysis of methyl iodide and the hydrogen halides. II. Photolysis of methyl iodide in the presence of iodine and the hydrogen halides
Journal:   J. Chem. Phys.
Volume:   15
Page(s):   696 - 702
Year:   1947
Reference type:   Journal article
Squib:   1947WIL/OGG696-702

Reaction:   ·CH3 + I2CH3I + I
Reaction order:   2
Reference reaction:   ·CH3 + HICH4 + I
Reference reaction order:   2
Temperature:   355 - 465 K
Pressure:  0.28 - 0.30 bar
Rate expression:   4.4 e3135 [J/mole]/RT
Bath gas:   CH3I
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
355 1.27E1
375 1.20E1
400 1.13E1
425 1.07E1
450 1.02E1
465 9.90E0