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Accessibility information
Author(s):   Barton, D.H.R.
Title:   The kinetics of the dehydrochlorination of substituted hydrocarbons. part I. Induced dehydrochlorination
Journal:   J. Chem. Soc. London
Page(s):   148 - 155
Year:   1949
Reference type:   Journal article
Squib:   1949BAR148-155

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1949BAR148-155   C2H5ClC2H4 + HCl  625 - 769   3.80E07       1.34E05      1
  1949BAR148-155   CH3CHCl2CH2=CHCl + HCl  667 - 833   5.89E07       1.42E05      1
  1949BAR148-155   CHCl2CCl3C2Cl4 + HCl  571 - 714   8.13E07       1.22E05      1
  1949BAR148-155   CH3CHClCH2Cl → Other Products + HCl  625 - 833   1.62E08       1.43E05      1
  1949BAR148-155   CH2ClCH2ClCH2=CHCl + HCl  625 - 870   1.59E06       1.13E05      1
  1949BAR148-155   CH3CHClCHCl2 → Other Products + HCl  625 - 769   5.50E09       1.59E05      1
  1949BAR148-155   Benzene, (2-chloroethyl)-Styrene + HCl  667 - 833   1.00E08       1.36E05      1
  1949BAR148-155   CH3CHClCHClCH3 → Other Products + HCl  625 - 769   5.13E07       1.27E05      1

Search returned 8 records.