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Accessibility information
Author(s):   Barton, D.H.R.
Title:   The kinetics of the dehydrochlorination of substituted hydrocarbons. part I. Induced dehydrochlorination
Journal:   J. Chem. Soc. London
Page(s):   148 - 155
Year:   1949
Reference type:   Journal article
Squib:   1949BAR148-155

Reaction:   CHCl2CCl3C2Cl4 + HCl
Reaction order:   1
Temperature:   571 - 714 K
Rate expression:   8.13x107 [s-1] e-122223 [J/mole]/RT
Bath gas:   CHCl2CCl3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
571 5.36E-4
575 6.42E-4
600 1.86E-3
625 4.96E-3
650 1.23E-2
675 2.83E-2
700 6.16E-2
714 9.31E-2