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Author(s):   Newton, T.W.; Rollefson, G.K.
Title:   The relative rates of photo-chlorination of CHCl3 and CDCl3
Journal:   J. Chem. Phys.
Volume:   17
Year:   1949
Reference type:   Journal article
Squib:   1949NEW/ROL718

Reaction:   CHCl3 + Cl·CCl3 + HCl
Reaction order:   2
Reference reaction:   CCl3D + Cl·CCl3 + DCl
Reference reaction order:   2
Temperature:   253 - 453 K
Rate expression:   1.4±2.0x10-1 e2968 [±8314472 J/mole]/RT
Bath gas:   Cl2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
253 5.74E0
275 5.13E0
300 4.60E0
325 4.20E0
350 3.88E0
375 3.63E0
400 3.42E0
425 3.24E0
450 3.10E0
453 3.08E0