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Accessibility information
Author(s):   Gomer, R.
Title:   The reaction of methyl radicals with n-butane
Journal:   J. Am. Chem. Soc.
Volume:   72
Year:   1950
Reference type:   Journal article
Squib:   1950GOM201

Reaction:   n-C4H10 + ·CH3 → Other Products + CH4
Reaction order:   2
Reference reaction:   (CH3)2Hg + ·CH3 → Other Products + CH4
Reference reaction order:   2
Temperature:   403 - 493 K
Pressure:  3.33E-2 - 5.33E-2 bar
Rate expression:   1.95 e2569 [J/mole]/RT
Bath gas:   (CH3)2Hg
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
403 4.20E0
425 4.03E0
450 3.87E0
475 3.74E0
493 3.65E0