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Accessibility information
Author(s):   Barton, D.H.R.; Head, A.J.; Williams, R.J.
Title:   The kinetics of the dehydrochlorination of substituted hydrocarbons. Part VIII. The mechanisms of the thermal decompositions of n-propyl and n-butyl chloride and 2 : 2'-dichlorodiethyl ether
Journal:   J. Chem. Soc.
Page(s):   2039 - 2046
Year:   1951
Reference type:   Journal article
Squib:   1951BAR/HEA2039-2046

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1951BAR/HEA2039-2046   n-C4H9Cl1-C4H8 + HCl  700 - 744   1.00E14       2.39E05      1
  1951BAR/HEA2039-2046   (ClCH2CH2)2O → Other Products + HCl  646 - 702   1.00E15       2.28E05      1
  1951BAR/HEA2039-2046   n-C3H7ClCH3CH=CH2 + HCl  693 - 751   2.82E13       2.39E05      1

Search returned 3 records.