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Accessibility information
Author(s):   Barton, D.H.R.; Head, A.J.; Williams, R.J.
Title:   The kinetics of the dehydrochlorination of substituted hydrocarbons. Part VIII. The mechanisms of the thermal decompositions of n-propyl and n-butyl chloride and 2 : 2'-dichlorodiethyl ether
Journal:   J. Chem. Soc.
Page(s):   2039 - 2046
Year:   1951
Reference type:   Journal article
Squib:   1951BAR/HEA2039-2046

Reaction:   n-C3H7ClCH3CH=CH2 + HCl
Reaction order:   1
Temperature:   693 - 751 K
Pressure:  6.67E-2 - 0.21 bar
Rate expression:   2.82x1013 [s-1] e-238625 [±8314472 J/mole]/RT
Uncertainty:   2.24000001
Bath gas:   n-C3H7Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
693 2.91E-5
700 4.41E-5
725 1.81E-4
750 6.78E-4
751 7.13E-4