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Author(s):   Anderson, H.R., Jr.; Scheraga, H.A.; VanArtsdalen, E.R.
Title:   Bromination of hydrocarbons. VI. Photochemical and thermal bromination of toluene. Bond dissociation energies
Journal:   J. Chem. Phys.
Volume:   21
Year:   1953
Reference type:   Journal article
Squib:   1953AND/SCH1258

Reaction:   Benzyl + HBrToluene + Br·
Reaction order:   2
Reference reaction:   Benzyl + Br2(Bromomethyl)benzene + Br·
Reference reaction order:   2
Temperature:   355 - 405 K
Pressure:  0.16 - 0.20 bar
Rate expression:   1.01x103 e-22532 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
355 4.89E-1
375 7.34E-1
400 1.15E0
405 1.25E0