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Accessibility information
Author(s):   Carrington, T.; Davidson, N.
Title:   Shock waves in chemical kinetics: The rate dissociation of N2O4
Journal:   J. Phys. Chem.
Volume:   57
Year:   1953
Reference type:   Journal article
Squib:   1953CAR/DAV418

Reaction:   N2O4NO2 + NO2
Reaction order:   1
Temperature:   253 - 301 K
Pressure:  0.51 - 7.09 bar
Rate expression:   1.0x1016 [s-1] e-54377 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
253 5.94E4
275 4.70E5
300 3.41E6
301 3.66E6