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Accessibility information
Author(s):   Dainton, F.S.; McElcheran, D.E.
Title:   The reaction CH3 + CD4 →’ CH3D + CD3
Journal:   Trans. Faraday Soc.
Volume:   51
Year:   1955
Reference type:   Journal article
Squib:   1955DAI/MCE657

Reaction:   (CH3)2CO + ·CH3CH4 + CH3C(O)CH2(·)
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   393 - 653 K
Pressure:  8.67E-2 - 0.16 bar
Rate expression:   8.3x10-13 [cm3/molecule s] e-40990 [J/mole]/RT
Bath gas:   CD4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
393 2.96E-18
400 3.69E-18
425 7.61E-18
450 1.45E-17
475 2.58E-17
500 4.34E-17
525 6.93E-17
550 1.06E-16
575 1.57E-16
600 2.24E-16
625 3.12E-16
650 4.22E-16
653 4.37E-16