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Author(s):   McNesby, J.R.; Gordon, A.S.
Title:   The photolysis and pyrolysis of acetone-d6 in the presence of ethane and of acetone in the presence of ethane-d6
Journal:   J. Am. Chem. Soc.
Volume:   77
Year:   1955
Reference type:   Journal article
Squib:   1955MCN/GOR4719

Reaction:   (CH3)2CO + ·CH3CH4 + CH3C(O)CH2(·)
Reaction order:   2
Reference reaction:   C2D6 + ·CH3CH3D + ·C2D5
Reference reaction order:   2
Temperature:   527 - 780 K
Pressure:  0.11 bar
Rate expression:   2.0x10-1 e21867 [±656 J/mole]/RT
Bath gas:   C2D6
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
527 2.94E1
550 2.39E1
575 1.94E1
600 1.60E1
625 1.34E1
650 1.14E1
675 9.84E0
700 8.57E0
725 7.52E0
750 6.67E0
775 5.95E0
780 5.83E0