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Accessibility information
Author(s):   Szwarc, M.; Taylor, J.W.
Title:   Pyrolysis of acetone and the heat of formation of acetyl radicals
Journal:   J. Chem. Phys.
Volume:   23
Page(s):   2310 - 2314
Year:   1955
Reference type:   Journal article
Squib:   1955SZW/TAY2310-2314

Reaction:   (CH3)2CO·CH3 + CH3CO
Reaction order:   1
Temperature:   993 - 1100 K
Pressure:  6.93E-3 - 2.80E-2 bar
Rate expression:   2.4x1014 [s-1] e-300984 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
993 3.53E-2
1000 4.56E-2
1025 1.10E-1
1050 2.56E-1
1075 5.70E-1
1100 1.22E0