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Accessibility information
Author(s):   Schubert, C.C.; Pease, R.N.
Title:   The oxidation of lower paraffin hydrocarbons. I. Room temperature reaction of methane, propane, n-butane and isobutane with ozonized oxygen
Journal:   J. Am. Chem. Soc.
Volume:   78
Page(s):   2044 - 2048
Year:   1956
Reference type:   Journal article
Squib:   1956SCH/PEA2044-2048

Reaction:   n-C4H10 + O3 → Products
Reaction order:   2
Temperature:   298 - 323 K
Pressure:  1.01 bar
Rate expression:   1.36x10-15 [cm3/molecule s] e-46395 [J/mole]/RT
Bath gas:   O3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.00E-23
300 1.14E-23
323 4.28E-23