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Accessibility information
Author(s):   Ackerman, M.; Chiltz, G.; Goldfinger, P.; Martens, G.
Title:   La specificite des halogenations atomiques. VI. - Reactions de competition
Journal:   Bull. Soc. Chim. Belg.
Volume:   66
Year:   1957
Reference type:   Journal article
Squib:   1957ACK/CHI325

Reaction:   C2Cl4 + ·Cl → C2Cl5
Reaction order:   2
Reference reaction:   CHCl2CCl3 + ·Cl → C2Cl5 + HCl
Reference reaction order:   2
Temperature:   360 - 560 K
Pressure:  0.11 - 0.17 bar
Rate expression:   6.31x10-3 e23946 [J/mole]/RT
Bath gas:   Cl2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
360 1.88E1
375 1.37E1
400 8.45E0
425 5.53E0
450 3.80E0
475 2.71E0
500 2.00E0
525 1.52E0
550 1.19E0
560 1.08E0