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Accessibility information
Author(s):   Goldfinger, P.; Jeunehomme, M.; Martens, G.
Title:   Energies and entropies of activation in chlorine atom reactions
Journal:   J. Chem. Phys.
Page(s):   456 - 458
Year:   1958
Reference type:   Journal article
Squib:   1958GOL/JEU456-458

Reaction:   C2Cl5 + ·ClC2Cl4 + Cl2
Reaction order:   2
Temperature:   358 - 563 K
Pressure:  1.60E-3 bar
Rate expression:   6.61x10-9 [cm3/molecule s] e-5014 [J/mole]/RT
Bath gas:   Cl2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
358 1.23E-9
375 1.32E-9
400 1.46E-9
425 1.60E-9
450 1.73E-9
475 1.86E-9
500 1.98E-9
525 2.10E-9
550 2.21E-9
563 2.26E-9