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Accessibility information
Author(s):   Goldfinger, P.
Title:   No. 15. - Les constantes de vitesse elementaires de quelques reactions de chloruration atomiques
Journal:   J. Chim. Phys.
Volume:   55
Page(s):   234 - 245
Year:   1958
Reference type:   Journal article
Squib:   1958GOL234-245

Reaction:   C2Cl4 + ·Cl → C2Cl5
Reaction order:   2
Reference reaction:   CHCl2CCl3 + ·Cl → C2Cl5 + HCl
Reference reaction order:   2
Temperature:   623 - 703 K
Rate expression:   3.55x10-3 e10809 [±108 J/mole]/RT
Uncertainty:   1.04999995
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
623 2.86E-2
625 2.84E-2
650 2.62E-2
675 2.44E-2
700 2.27E-2
703 2.26E-2