Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Boddy, P.J.; Steacie, E.W.R.
Title:   Hydrogen atom abstraction by ethyl-d5 radicals. Part I
Journal:   Can. J. Chem.
Volume:   38
Page(s):   1576 - 1589
Year:   1960
Reference type:   Journal article
Squib:   1960BOD/STE1576-1589

Reaction:   n-C4H10 + ·C2D5 → Other Products + C2HD5
Reaction order:   2
Reference reaction:   CD3CD2C(O)CD2CD3 + ·C2D5 → Other Products + C2D6
Reference reaction order:   2
Temperature:   323 - 573 K
Pressure:  2.93E-2 - 0.28 bar
Rate expression:   1.21 e-5770 [±634 J/mole]/RT
Uncertainty:   1.23000002
Bath gas:   n-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
323 1.41E-1
325 1.43E-1
350 1.67E-1
375 1.90E-1
400 2.13E-1
425 2.36E-1
450 2.59E-1
475 2.81E-1
500 3.02E-1
525 3.23E-1
550 3.43E-1
573 3.60E-1