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Accessibility information
Author(s):   McMillan, G.R.
Title:   Photolysis of di-t-butyl peroxide-azomethane and ei-t-butyl peroxide-isobutane mixtures
Journal:   J. Am. Chem. Soc.
Volume:   82
Year:   1960
Reference type:   Journal article
Squib:   1960MCM2422

Reaction:   (CH3)3CO → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   297 - 324 K
Pressure:  2.67E-2 bar
Rate expression:   1.0x1011 [s-1] e-46062 [J/mole]/RT
Bath gas:   (tert-C4H9O)2
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
297 7.93E2
300 9.55E2
324 3.75E3