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Title: Photolysis of di-t-butyl peroxide-azomethane and ei-t-butyl peroxide-isobutane mixtures
Journal: J. Am. Chem. Soc.
Volume: 82
Page(s):
Year: 1960
Reference type: Journal article
Squib: 1960MCM2422
Reaction:
(CH3)3CO → (CH3)2CO + ·CH3
Reaction order:
1
Temperature:
297 - 324
K
Pressure: 2.67E-2 bar
Rate expression:
1.0x1011 [s-1] e-46062 [J/mole]/RT
Bath gas:
(tert-C4H9O)2
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 297 | 7.93E2 |
| 300 | 9.55E2 |
| 324 | 3.75E3 |