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Accessibility information
Author(s):   Shaw, R.; Trotman-Dickenson, A.F.
Title:   The reactions of methoxyl radicals with alkanes
Journal:   J. Chem. Soc.
Year:   1960
Reference type:   Journal article
Squib:   1960SHA/TRO3210

Reaction:   iso-C4H10 + CH3 → Other Products + CH3OH
Reaction order:   2
Reference reaction:   C3H8 + CH3 → Other Products + CH3OH
Reference reaction order:   2
Temperature:   573 - 673 K
Rate expression:   4.2x10-1 e5438 [±8314472 J/mole]/RT
Uncertainty:   1.48000002
Bath gas:   CH3ONO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
573 1.32E0
575 1.31E0
600 1.25E0
625 1.20E0
650 1.15E0
673 1.11E0