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Accessibility information
Author(s):   Wijnen, M.H.J.
Title:   Reactions of alkoxy radicals. VII. The ethoxy radical
Journal:   J. Am. Chem. Soc.
Volume:   82
Page(s):   3034 - 3040
Year:   1960
Reference type:   Journal article
Squib:   1960WIJ3034-3040

Reaction:   C2H5COOC2H5 + CH3CH2 → Other Products + C2H5OH
Reaction order:   2
Reference reaction:   CH3CH2CH2O + ·CH3
Reference reaction order:   1
Temperature:   292 - 468 K
Pressure:  7.20E-3 - 4.00E-2 bar
Rate expression:   5.65x10-52 [cm3/molecule] e27438 [J/mole]/RT
Bath gas:   C2H5COOC2H5
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule]
292 4.57E-47
300 3.38E-47
325 1.45E-47
350 7.02E-48
375 3.75E-48
400 2.16E-48
425 1.33E-48
450 8.64E-49
468 6.52E-49