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Accessibility information
Author(s):   Berces, T.; Trotman-Dickenson, A.F.
Title:   The reactions of methoxyl radicals with cyclopropane and isobutane
Journal:   J. Chem. Soc.
Year:   1961
Reference type:   Journal article
Squib:   1961BER/TRO348

Reaction:   C2H6 + CH3CH3OH + ·C2H5
Reaction order:   2
Reference reaction:   Cyclopropane + CH3CH3OH + Cyclopropyl
Reference reaction order:   2
Temperature:   468 - 597 K
Rate expression:   7.11x10-1 e11225 [±8314472 J/mole]/RT
Uncertainty:   1.32000005
Bath gas:   (CH3O)2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
468 1.27E1
475 1.22E1
500 1.06E1
525 9.30E0
550 8.28E0
575 7.44E0
597 6.82E0