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Author(s):   Goldfinger, P.; Huybrechts, G.; Martens, G.
Title:   Elementary rate constants in atomic chlorination reactions. Part 2.-Experiments in competitive systems
Journal:   Trans. Faraday Soc.
Volume:   57
Page(s):   2210 - 2219
Year:   1961
Reference type:   Journal article
Squib:   1961GOL/HUY2210-2219

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1961GOL/HUY2210-2219	CHCl₃ + ·Cl → ·CCl₃ + HCl	357 - 477	2.62E-11	1.40E04	2
1961GOL/HUY2210-2219	CH₄ + ·Cl → ·CH₃ + HCl	357 - 477	8.32E-11	1.61E04	2
1961GOL/HUY2210-2219	CH₃Cl + ·Cl → ·CH₂Cl + HCl	357 - 477	5.25E-11	1.29E04	2
1961GOL/HUY2210-2219	CH₂Cl₂ + ·Cl → CHCl₂ + HCl	357 - 477	4.17E-11	1.31E04	2
1961GOL/HUY2210-2219	CHCl₂CCl₃ + ·Cl → C₂Cl₅ + HCl	357 - 477	1.05E-11	1.38E04	2
1961GOL/HUY2210-2219	C₂Cl₄ + ·Cl → C₂Cl₅	357 - 477	4.17E-12		2

Search returned 6 records.