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Accessibility information
Author(s):   Grzechowiak, J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Hydrogen abstraction by difluoroamino-radicals and the strengths of C-H bonds
Journal:   J. Chem. Soc. Chem. Commun.
Page(s):   109 - 110
Year:   1961
Reference type:   Journal article
Squib:   1961GRZ/KER109-110

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1961GRZ/KER109-110   iso-C4H10 + NF2tert-C4H9 + HNF2  428 - 555   5.13E-14       7.73E04      2
  1961GRZ/KER109-110   n-C4H10 + NF2 → Other Products + HNF2  453 - 555   1.12E-12       9.31E04      2
  1961GRZ/KER109-110   Cyclopentane + NF2Cyclopentyl + HNF2  453 - 555   1.41E-13       8.31E04      2
  1961GRZ/KER109-110   neo-C5H12 + NF2(CH3)3CCH2 + HNF2  453 - 555   2.76E-11       1.11E05      2

Search returned 4 records.