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Author(s):   Grzechowiak, J.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   Hydrogen abstraction by difluoroamino-radicals and the strengths of C-H bonds
Journal:   J. Chem. Soc. Chem. Commun.
Page(s):   109 - 110
Year:   1961
Reference type:   Journal article
Squib:   1961GRZ/KER109-110

Reaction:   n-C4H10 + NF2 → Other Products + HNF2
Reaction order:   2
Temperature:   453 - 555 K
Rate expression:   1.12x10-12 [cm3/molecule s] e-93122 [±333 J/mole]/RT
Uncertainty:   1.10000002
Bath gas:   N2F4
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
453 2.05E-23
475 6.46E-23
500 2.10E-22
525 6.10E-22
550 1.61E-21
555 1.93E-21