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Accessibility information
Author(s):   Buckley, E.; Whittle, E.
Title:   Photobromination of methanol. Part 3.-Kinetics in the presence of added carbon dioxide
Journal:   Trans. Faraday Soc.
Volume:   58
Year:   1962
Reference type:   Journal article
Squib:   1962BUC/WHI536

Reaction:   CH3OH + Br·(·)CH2OH + HBr
Reaction order:   2
Reference reaction:   Br· + Br·Br2
Temperature:   349 - 367 K
Pressure:  0.44 - 0.56 bar
Rate expression:   7.59x10-13 [cm3/molecule s] (T/298 K)0.50 e-25941 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
349 1.08E-16
350 1.11E-16
367 1.71E-16