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Accessibility information
Author(s):   Duncan, F.J.; Trotman-Dickenson, A.F.
Title:   The reactions of phenyl radicals from the photolysis of acetophenone and the strength of the C-H bond in benzene
Journal:   J. Chem. Soc.
Page(s):  
Year:   1962
Reference type:   Journal article
Squib:   1962DUN/TRO4672

Reaction:   iso-C4H10 + Phenyl → Other Products + Benzene
Reaction order:   2
Temperature:   550 - 680 K
Pressure:  1.87E-2 - 8.00E-2 bar
Rate expression:   1.05x10-12 [cm3/molecule s] e-28020 [J/mole]/RT
Bath gas:   1-Phenylethanone
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
550 2.29E-15
575 2.98E-15
600 3.81E-15
625 4.77E-15
650 5.87E-15
675 7.11E-15
680 7.38E-15